Alumina Technology (CETI Enterprises)
Sunday, May 12, 2024
Monday, November 20, 2023
Is Low Silica in Bauxite a Problem?
Hi Friends,
After a long gap, I have appeared before you to interact on a
small but very critical process issue of Bayer Alumina Plant.
In the past, we have always discussed about the negative
impact of high silica in bauxite specifically with regard to operational
problems, process control issues, higher consumption of input materials and deterioration
in quality of product hydrate or alumina. In previous articles, this issue was
elaborated at length with measurable / quantifiable approach so as to focus on
its importance in Bayer Alumina Refineries.
In present post, we will briefly discuss about the advantages
and disadvantages of low silica in processing bauxite for production of
calcined alumina. The question mark (?) on the subject itself forces us to think
and re-think about the positive and negative aspects of low silica in bauxite.
It’s a well-known fact that all Alumina producers wish to
have low silica bauxite for obvious reasons discussed earlier. Now, before coming
to the subject directly, following questions arise-
(i)
What
type of silica is harmful for Bayer’s process?
(ii)
What
should be the cut-off silica content in bauxite for acceptable quality of
alumina in International market?
Though we have discussed these issues in several articles,
still it is prudent to freshen up with salient features as outlined below-
There are two types of silica in bauxite designated with
regard to Bayer process of alumina – (a) Non-reactive silica and (b) Reactive
silica. ROM bauxite mined adopting either open cast or underground mining
methodology contains a number of metallic oxides including silica. This mined
silica as percentage of total dry bauxite is termed as total silica. The part
of total silica which reacts with caustic soda and forms sodalite complex
through sodium silicate route is termed as Reactive silica. Majority of
Reactive silica is found in form of Kaolinite. And thus, the non-reacting
component of total silica with caustic soda is popularly known as Non-reactive
silica. Quartz is non-reactive silica. The silica being abrasive in nature
causes erosion in components of various process equipment like heat exchangers,
pipelines, valves, pump casing and impellers etc. Thus higher silica content
affects the capital investment of Alumina refinery because robust material of
construction for equipment component in contact with bauxite slurry. Hence
higher silica in bauxite causes higher initial investment for the plant and
higher repair maintenance cost for routine replacement of critical components
of equipment.
Generally it has been seen from bauxite analysis that
Reactive silica in bauxite ranges from 50% to 80% out of Total silica in
bauxite. Plant operation is affected because of high silica in bauxite as it
has high settling velocity and abnormally high abrasive nature.
Now coming to the topic with raised question mark, it’s true
that low reactive silica in bauxite is considered as a serious process problem
as it directly affects the quality of product alumina because of higher silica
content in alumina. The SiO2 content in calcined alumina produced in
all modern alumina a refinery is controlled at around 0.015%. The alumina
having higher silica content is considered as inferior quality. For achieving
0.015% SiO2 in alumina, the SiO2 in aluminate liquor
feeding to crystallizers / precipitators should be around 0.45 gpl. The saturation level of silica in aluminate liquor is about 3.80 gpl SuO2 which is achieved within an hour in desilication circuit. The delay
in achieving super-saturation of silica across desilication tanks results in inefficient desilication thereby increasing gpl SiO2 in
liquor increases to much higher level which ultimately deteriorates the product
alumina quality.
The above elaboration concludes that moderate level of
Reactive silica in bauxite at around 1.5% in bauxite is considered to be the
best with regard to plant efficiencies and product quality as well.
Trust, the subject has
been covered here to your desired level of satisfaction in understanding the
criticality of the subject issue. We would welcome your valued comments / remarks to further
substantiate the subject.
Regards.
Founder & CEO
CETI Enterprises, Delhi NCR, India
Cell: +91 8380043065
Wednesday, July 15, 2020
Efficient Bauxite Grinding System for Alumina Refinery
- Bond index of bauxite,
- Grinding rate,
- Feed size (F80),
- Product size (P80)
Kindly put your views / suggestions / remarks / comments, if any on the subject.
If you like this article, then please press your rating as +1 .
Thanks and regards.
Tuesday, May 5, 2020
System Design Calculations for Setting up Refractory Grade Alumina Refinery
In present post, we will discuss about the product specifications, production process route and system design including list of major equipment for a typical RGA plant of 3000 tpa production capacity in subsequent paragraphs-
Typical analysis of Fuel oil:-
Thanks and regards.
www.ceti.co.in
Sunday, May 3, 2020
Preferred Classification Equipment for Ground Bauxite Slurry
- DSM Screens,
- Banana Screens,
- Hydro-cyclones.
I personally like trouble-free operation of hydro-cyclones over others and love to operate it efficiently. This is purely my personal experience. In case, you differ to my views, please come forward in freely exchanging your own operating experience. We will welcome your views.
regards.
Rajendra Kunwar
www.ceti.co.in
Saturday, May 2, 2020
Basic Approach for Testing & Commissioning of Alumina Refinery
- Formation of team comprising of Managers of various disciplines / departments headed by an Expert.
- Train the Supervisors aiming to ‘Train the Trainer’ who will train the operators,
- Review the start up and commissioning procedures,
- Educating the team with operating and process control parameters including benefits and consequences,
- Provide technical leadership to facilitate safe, reliable and steady operation of Alumina refinery.
· Production of hydrate and product alumina.
Performance Tests for Plant and Equipment:
Test runs are conducted with standard agreed procedure for individual plant, equipment and facilities in order to assess the guaranteed performance. However, performance tests for entire Alumina refinery are carried out after stabilization of plant operation to check the assigned production rate and efficiency parameters as agreed by technology supplier, equipment supplier and engineering consultant.
Principal Consultant-Engineering
CETI Enterprises,
www.ceti.co.in
Saturday, April 11, 2020
REASONS FOR HIGH READERS TRAFFIC ON ALUMINA TECHNOLOGY BLOG
- Unique technical platform with authentic data and information,
- Terminology nicely elaborated for easy understanding,
- Detailed process and engineering calculations with systematic approach,
- Process and control parameters elaborated with clarity,
- Equipment design calculations presented with suitable examples,
- Methodology described for project costing and production costing,
- A to Z from bauxite mining to Alumina production in detail with glimpse of aluminium production technology,
- Detailed specifications for variety of bauxite, alumina and alumina chemicals,
- Good coverage on production process of each product with focus on market perspective, demand and project profitability,
- Benchmark figures on efficiency parameters such as raw material consumption figures and energy consumption aspects,
- Process of developing basic engineering documents for all unit operation and processes including design of Residue storage pond,
- Simplicity in presentation highlighting important steps.